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Free, publicly-accessible full text available January 1, 2026
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Abstract As the demand for clean water intensifies, developing effective methods for removing pollutants from contaminated sources becomes increasingly crucial. This work establishes a method for additive manufacturing of functional polymer sorbents with hollow porous features, designed to enhance interactions with organic micropollutants. Specifically, core–shell filaments are used as the starting materials, which contain polypropylene (PP) as the shell and poly(acrylonitrile‐co‐butadiene‐co‐styrene) as the core, to fabricate 3‐dimensional (3D) structures on‐demand via material extrusion. After 3D printing, the cores of the printed roads are removed through solvent extraction, creating hollow structures that increase accessible surface area for adsorption. Subsequently, a sulfonation‐induced crosslinking reaction installs sulfonic acid functionalities into the PP backbones, while enhancing their chemical stability. It is found that larger voids, and thinner polymer shells, enable improved structural retention during the sulfonation through limiting reaction‐induced stresses. The hollow sulfonated PP sorbents exhibit a strong affinity against cationic pollutants. Specifically, larger voids within these structures not only improve structural integrity but also result in accelerated adsorption kinetics by maximizing accessible surface area, thereby enhancing pollutant removal efficiency. This work provides a promising solution for advanced structured sorbent fabrication with hollow architectures, leading to more effective solutions for water contaminant removal in the future.more » « less
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Ultra-wide bandgap (UWBG) semiconductors are promising for many applications, such as power electronics and deep-ultraviolet photonics. In this research, UWBG β-phase magnesium gallium oxide (MgGaO) thin films with a bandgap of 5.1 eV were grown using low-temperature homo-buffer layers in a plasma-assisted molecular beam epitaxy system. The role of the growth temperature and thickness of low-temperature buffer layer on the quality of the active layer was studied using x-ray diffraction and transmission electron microscopy and by analyzing the properties of metal–semiconductor–metal photodetector devices based on these films. It is found that lower buffer growth temperature at 300 °C leads to higher crystal quality of active layer. For the same low buffer growth temperature, different crystal quality in the active layer is attained with different buffer layer thickness. A buffer layer thickness at 40 nm has the best active layer quality with the highest photo current under 265 nm illumination and long decay time as a result of reduced recombination of photo-generated carriers through fewer defects in the active layer.more » « less
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Information seeking is crucial for people's self-care and wellbeing in times of public crises. Extensive research has investigated empirical understandings as well as technical solutions to facilitate information seeking by domestic citizens of affected regions. However, limited knowledge is established to support international migrants who need to survive a crisis in their host countries. The current paper presents an interview study with two cohorts of Chinese migrants living in Japan (N=14) and the United States (N=14). Participants reflected on their information seeking experiences during the COVID pandemic. The reflection was supplemented by two weeks of self-tracking where participants maintained records of their COVID-related information seeking practice. Our data indicated that participants often took language detours, or visits to Mandarin resources for information about the COVID outbreak in their host countries. They also made strategic use of the Mandarin information to perform selective reading, cross-checking, and contextualized interpretation of COVID-related information in Japanese or English. While such practices enhanced participants' perceived effectiveness of COVID-related information gathering and sensemaking, they disadvantaged people through sometimes incognizant ways. Further, participants lacked the awareness or preference to review migrant-oriented information that was issued by the host country's public authorities despite its availability. Building upon these findings, we discussed solutions to improve international migrants' COVID-related information seeking in their non-native language and cultural environment. We advocated inclusive crisis infrastructures that would engage people with diverse levels of local language fluency, information literacy, and experience in leveraging public services.more » « less
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